HRID1720809

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID6422

未命名化合物

HCID11593431

未命名化合物

结构：CCCCCCCCCCCCCCCC(=O)OCC(CSCCC(=O)NCC(=O)NCC(=O)OC(C)(C)C)OC(=O)CCCCCCCCCCCCCCC

HCID22418588

未命名化合物

PRODUCTS

生成物

结构：CCCCCCCCCCCCCCCC(=O)OCC(CSCCC(=O)NCC(=O)NCC(=O)O)OC(=O)CCCCCCCCCCCCCCC

HCID22353662

未命名化合物

收率 100%

PROCEDURE

实验过程

To (6,7-bis(palmitoyloxy)-4-thiaheptanoyl)glycylglycine t-butyl ester as obtained in Example 3 (190 mg), trifiuoroacetic acid (2 ml) was added, followed by stirring at room temperature for I hour. The mixture was concentrated to yield the title compound (178 mg, yield 100%) as a colorless crystal.

WORKUP

后处理

additionwas added
concentrationThe mixture was concentrated

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-07334b6b527449bfa0c585077a279f1e
来源数据集: uspto-grants-1996_04
DOI: 10.6084/m9.figshare.5104873.v1
专利: US05506267
来源说明: uspto-grants-1996_04

反应 SMILES

C([O:5][C:6](=[O:57])[CH2:7][NH:8][C:9](=[O:56])[CH2:10][NH:11][C:12](=[O:55])[CH2:13][CH2:14][S:15][CH2:16][CH:17]([O:37][C:38](=[O:54])[CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH3:53])[CH2:18][O:19][C:20](=[O:36])[CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH3:35])(C)(C)C.O1CC1C(O)C.FC(F)(F)C(O)=O>>[C:38]([O:37][CH:17]([CH2:18][O:19][C:20](=[O:36])[CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH3:35])[CH2:16][S:15][CH2:14][CH2:13][C:12]([NH:11][CH2:10][C:9]([NH:8][CH2:7][C:6]([OH:57])=[O:5])=[O:56])=[O:55])(=[O:54])[CH2:39][CH2:40][CH2:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH3:53]