Triethylamine → HCID 14989152, compound

HRID 1722797Notes

Reaction equation

HRID 1722797 reaction equation
[CH3:1][C:2]([C:5]1[CH:10]=[C:9]([SH:11])[CH:8]=[C:7]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:6]=1[OH:16])([CH3:4])[CH3:3].[CH2:17]([C:19]([CH:21]=[CH2:22])=[O:20])[CH3:18].C(N(CC)CC)C>CO>[CH3:4][C:2]([C:5]1[CH:10]=[C:9]([S:11][CH2:18][CH2:17][C:19](=[O:20])[CH2:21][CH3:22])[CH:8]=[C:7]([C:12]([CH3:15])([CH3:14])[CH3:13])[C:6]=1[OH:16])([CH3:1])[CH3:3]

Participants

5

Reactant 3

HCID 8471TriethylamineHCID 153941-Penten-3-oneHCID 703702,6-Di-tert-butyl-4-mercaptophenol

Product 1

HCID 14989152HCID 14989152, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

The title compound of Example 2 (5.0 g, 0.021 mole) was reacted with ethylvinyl ketone (6.3 ml) and triethylamine (1 ml) in methanol (30 ml) by the method of Example 3 to give the title compound, m.p. ca. 76°-79° C. Analysis calc. for C19H30O2S(332.50):

Sources & evidence

ORD record
ord-19527d7f08ec4eb29bafb4f3990624b7
Source dataset
uspto-grants-1989_08
Patent number
US04857558

Reaction notes

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