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HRID1726067

反应详情

EQUATION

反应方程式

HRID 1726067 的结构方程式

REACTANTS

反应物

3
结构：O=[N+]([O-])c1ccc(O)cc1
HCID980

4-Nitrophenol

C6H5NO3

结构：CP(=O)(Cl)Cl
HCID12671

Methylphosphonic acid dichloride

CH3Cl2OP

结构：[H-].[Na+]
HCID24758

Sodium hydride

HNa

PRODUCTS

生成物

1
结构：CP(=O)(Oc1ccc([N+](=O)[O-])cc1)Oc1ccc([N+](=O)[O-])cc1
HCID98876

Bis(4-nitrophenyl) methylphosphonate

C13H11N2O7P

收率 88%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：C1CCOC1
溶剂HCID8028

Tetrahydrofuran

C4H8O

PROCEDURE

实验过程

Methylphosphonic acid bis-(4-nitrophenyl) ester is prepared according to procedure E using 1 g of 4-nitrophenol, 12 ml of THF, 345 mg of sodium hydride at 50% in oil and 478 mg of methylphosphonic dichloride. 1.07 g of crude methylphosphonic acid bis-(4-nitrophenyl) ester are obtained.

WORKUP

后处理

  1. customMethylphosphonic acid bis-(4-nitrophenyl) ester is prepared