Hydrogen Peroxide → HCID 54430564, compound

HRID 1730754Notes

Reaction equation

HRID 1730754 reaction equation
[CH:1]([NH:4][C:5](=[O:23])[CH2:6][S:7][CH2:8][C:9]([C:11]1[CH:16]=[CH:15][C:14]([C:17]2[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=2)=[CH:13][CH:12]=1)=[O:10])([CH3:3])[CH3:2].[OH:24]O>C(O)(=O)C>[CH:1]([NH:4][C:5](=[O:23])[CH2:6][S:7]([CH2:8][C:9]([C:11]1[CH:12]=[CH:13][C:14]([C:17]2[CH:18]=[CH:19][CH:20]=[CH:21][CH:22]=2)=[CH:15][CH:16]=1)=[O:10])=[O:24])([CH3:3])[CH3:2]

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 54086859HCID 54086859, compound

Product 1

HCID 54430564HCID 54430564, compoundYield 71.4%

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

A suspension of 2.0 gm (6.1 millimols) of [2-(4-biphenylyl)-2-oxo-ethylthio]-acetic acid isopropylamide in 20 ml of glacial acetic acid was admixed with 1.3 ml of 30% hydrogen peroxide, and the mixture was stirred at room temperature for 2 hours. The reaction product was precipitated with water and recrystallized from ethyl acetate after drying. Yield: 71.4% of theory; m.p. 138°-1/3°C.

Workup

  1. customThe reaction product was precipitated with water
  2. customrecrystallized from ethyl acetate
  3. customafter drying

Sources & evidence

ORD record
ord-c6bbd5ed207c4a69adb258a2a6f85c7d
Source dataset
uspto-grants-1976_11
Patent number
US03993683

Reaction notes

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