1-Dodecanol → HCID 560129, compound

HRID 1731211Notes

Reaction equation

HRID 1731211 reaction equation
[CH:1]1([C:4](Cl)=[O:5])[CH2:3][CH2:2]1.[CH2:7]([OH:19])[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]>C1C=CC=CC=1.CCCCC>[CH:1]1([C:4]([O:19][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18])=[O:5])[CH2:3][CH2:2]1

Participants

5

Reactant 2

HCID 81931-DodecanolHCID 77637Cyclopropanecarbonyl chloride

Product 1

HCID 560129HCID 560129, compound

Reagents, catalysts & solvents 2

HCID 241BenzeneSolventHCID 8003PentaneSolvent

Procedure

To a stirred solution of 2.25 g. of cyclopropane carboxylic acid chloride in dry benzene, under nitrogen, is added 8 g. of 1-dodecanol. The mixture is stirred overnight and then diluted with pentane. The reaction mixture is worked up by washing with water and brine and then removing the solvent to yield dodecyl cyclopropanecarboxylate, b.p. 99°-100° (bath) at 0.03 mm. (I; p" is zero, R is n-dodecyl).

Workup

  1. washby washing with water and brine
  2. customremoving the solvent

Sources & evidence

ORD record
ord-3216a9ff0cc442108ca9d6022d7908bc
Source dataset
uspto-grants-1976_11
Patent number
US03995054

Reaction notes

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