Potassium Carbonate → HCID 178444947, compound

HRID 1731281Notes

Reaction equation

HRID 1731281 reaction equation
[OH:1][C:2]1[CH:7]=[CH:6][C:5]([C@H:8]2[CH2:13][CH2:12][C@H:11]([C@H:14]3[CH2:19][CH2:18][C@H:17]([CH2:20][CH2:21][CH3:22])[CH2:16][CH2:15]3)[CH2:10][CH2:9]2)=[CH:4][CH:3]=1.C([O-])([O-])=O.[K+].[K+].[CH2:29](I)[CH2:30][CH2:31][CH2:32][CH2:33][CH3:34]>CN(C=O)C>[CH2:29]([O:1][C:2]1[CH:7]=[CH:6][C:5]([C@H:8]2[CH2:9][CH2:10][C@H:11]([C@H:14]3[CH2:19][CH2:18][C@H:17]([CH2:20][CH2:21][CH3:22])[CH2:16][CH2:15]3)[CH2:12][CH2:13]2)=[CH:4][CH:3]=1)[CH2:30][CH2:31][CH2:32][CH2:33][CH3:34]

Participants

5

Reactant 3

HCID 11430Potassium CarbonateHCID 125271-IodohexaneHCID 178448019HCID 178448019, compound

Product 1

HCID 178444947HCID 178444947, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

A mixture of 30 g of trans-1-p-hydroxyphenyl-4-(trans-4-propylcyclohexyl)-cyclohexane, 6.9 g of K2CO3, 25 g of hexyl iodide and 250 ml of DMF is heated to 80° for 16 hours, while stirring, and is then cooled and worked up in the customary manner. Trans-1-p-hexoxyphenyl-4-(trans-4-propylcyclohexyl)-cyclohexane is obtained.

Workup

  1. temperatureis heated to 80° for 16 hours
  2. temperatureis then cooled

Sources & evidence

ORD record
ord-5d7811c71e1b4d0a8aa85eddb90f354c
Source dataset
uspto-grants-1986_11
Patent number
US04620938

Reaction notes

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