HCID 131711967, compound → 4-Chlorobenzyl alcohol

HRID 1732855Notes

Reaction equation

HRID 1732855 reaction equation
C(=O)([O-])OCC[C:5](=[O:13])[C:6]1[CH:11]=[CH:10][C:9]([Cl:12])=[CH:8][CH:7]=1>[Pd].C(O)(=O)C>[Cl:12][C:9]1[CH:10]=[CH:11][C:6]([CH2:5][OH:13])=[CH:7][CH:8]=1

Participants

4

Reactant 1

HCID 131711967HCID 131711967, compound

Product 1

HCID 133974-Chlorobenzyl alcoholYield 82.1%

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 176Acetic AcidSolvent

Procedure

100 ml of glacial acetic acid and 5 g of 5% Pd on C are added to a solution of p-chlorobenzoyl-ethyl carbonate (22.8 g=0.1 moles). The mixture is reduced in a PARR apparatus for 10 hours at 60° and under a pressure of 200 psi (14 atm) of H2. We proceed as in Example II. We obtain 11.7 g (82%) of a product having the following characteristics:

Sources & evidence

ORD record
ord-6f6d8ef2ec9e400f986c7872f65b62ff
Source dataset
uspto-grants-1980_12
Patent number
US04239702

Reaction notes

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