Trichloromethanesulfenyl chloride → HCID 20300405, compound

HRID 1733158Notes

Reaction equation

HRID 1733158 reaction equation
[Na].[N+:2]([C:5]1[C:13]2[N:12]=[N:11][NH:10][C:9]=2[CH:8]=[CH:7][CH:6]=1)([O-:4])=[O:3].[Cl:14][C:15]([Cl:19])([Cl:18])[S:16]Cl>O>[N+:2]([C:5]1[C:13]2[N:12]=[N:11][N:10]([S:16][C:15]([Cl:19])([Cl:18])[Cl:14])[C:9]=2[CH:8]=[CH:7][CH:6]=1)([O-:4])=[O:3]

Participants

5

Reactant 3

HCID 11666Trichloromethanesulfenyl chlorideHCID 5360545SodiumHCID 178526563HCID 178526563, compound

Product 1

HCID 20300405HCID 20300405, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A solution of 10.2 grams of the sodium salt of 4-nitrobenzotriazole, 6 milliliters of trichloromethylsulfenyl chloride and 100 milliliters of water is stirred at 5° C. for 1 hour. The brown solid is collected by filtration and washed with ethyl ether. The crude product weighs 9.3 grams (51%) and recrystallized from carbon tetrachloride, m.p. 136.5°-137.5° C.

Workup

  1. filtrationThe brown solid is collected by filtration
  2. washwashed with ethyl ether
  3. customrecrystallized from carbon tetrachloride, m.p. 136.5°-137.5° C.

Sources & evidence

ORD record
ord-23248100907e47ebab737027444dbd28
Source dataset
uspto-grants-1980_12
Patent number
US04240822

Reaction notes

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