Benzaldehyde → HCID 178460710, compound

HRID 1733375Notes

Reaction equation

HRID 1733375 reaction equation
[C:1]([N:5]=[C:6]([S:19][CH3:20])[NH:7][C:8]1[CH:14]=[C:13]([S:15][CH2:16][CH2:17][CH3:18])[CH:12]=[CH:11][C:9]=1[NH2:10])([O:3][CH3:4])=[O:2].[CH:21](=O)[C:22]1[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=1>CO>[NH:10]=[C:9]1[CH:11]=[CH:12][C:13]([S:15][CH2:16][CH2:17][CH3:18])=[C:14]([CH2:21][C:22]2[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=2)[CH:8]1[NH:7][C:6](=[N:5][C:1]([O:3][CH3:4])=[O:2])[S:19][CH3:20]

Participants

4

Reactant 2

HCID 240BenzaldehydeHCID 178460736HCID 178460736, compound

Product 1

HCID 178460710HCID 178460710, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Conditions

Temperature
5 °C

Procedure

To a mixture of 2-(3-carbomethoxy-S-methylisothioureido)-4-propylthioaniline (3.13 g.; 0.01 mol) in methanol (25 ml.), cooled to 5° C., there is added benzaldehyde (1.06 g.; 0.1 mol). The mixture is stirred at room temperature for one hour and is filtered. The filter cake is dried to afford 1-iminophenylmethyl-2-(3-carbomethoxy-S-methylisothioureido)-4-propylthiobenzene.

Workup

  1. filtrationis filtered
  2. customThe filter cake is dried

Sources & evidence

ORD record
ord-3a9f3dd9703d484388f7276729e85dea
Source dataset
uspto-grants-1980_12
Patent number
US04241079

Reaction notes

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