Styrene → HCID 23460087, compound

HRID 1733423Notes

Reaction equation

HRID 1733423 reaction equation
[Cl:1][SiH2:2][Cl:3].[CH2:4]=[CH:5][C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1>[H+].[H+].Cl[Pt-2](Cl)(Cl)(Cl)(Cl)Cl.C(O)(C)C>[CH2:4]([Si:2]([CH2:4][CH2:5][C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)([Cl:3])[Cl:1])[CH2:5][C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1

Participants

5

Reactant 2

HCID 7501StyreneHCID 61330Dichlorosilane

Product 1

HCID 23460087HCID 23460087, compound

Reagents, catalysts & solvents 2

HCID 61859Chloroplatinic acidCatalystHCID 3776IsopropanolSolvent

Conditions

Temperature
50 °C

Procedure

30.0 g (300 millimol) of dichlorosilane, 56.5 g (543 millimol) of styrene and 50 ml of an isopropanol solution of chloroplatinic acid [H2PtCl6.6H2O (4.83×10-6 mol)] were charged in a 200 ml pressure-proof stainless steel reaction tube and reaction was carried out as in example 3 by heating in an oil bath at 50° C. for 15 hours with stirring. After reaction, the reacted liquid resinified and no diphenethyldichlorosilane was obtained.

Workup

  1. customAfter reaction

Sources & evidence

ORD record
ord-32eaae83769f4e3483d595fe470fe73a
Source dataset
uspto-grants-1980_12
Patent number
US04242272

Reaction notes

Loading…