Potassium Carbonate → HCID 19068977, compound

HRID 1735099Notes

Reaction equation

HRID 1735099 reaction equation
[CH3:1][N:2]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][C:9]=2[Cl:11])[C:4]([CH:12]=O)=[C:3]1Cl.C([O-])([O-])=O.[K+].[K+].[SH:21][CH2:22][C:23]([O:25][CH3:26])=[O:24]>>[Cl:11][C:9]1[CH:8]=[CH:7][CH:6]=[C:5]2[C:10]=1[N:2]([CH3:1])[C:3]1[S:21][C:22]([C:23]([O:25][CH3:26])=[O:24])=[CH:12][C:4]2=1

Participants

4

Reactant 3

HCID 11430Potassium CarbonateHCID 16907Methyl ThioglycolateHCID 19068945HCID 19068945, compound

Product 1

HCID 19068977HCID 19068977, compoundYield 83%

Procedure

Prepared from (47) (6.5 g), K2CO3 (11.17 g) and methyl 2-mercaptoacetate (4.46 ml) yielding (50) 6.62 g (83%). M.p. 166°-168° C.

Sources & evidence

ORD record
ord-50ac3be08c1f41dab716761009129cdd
Source dataset
uspto-grants-1996_07
Patent number
US05536721

Reaction notes

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