Sodium Iodide → HCID 19437009, compound

HRID 1735182Notes

Reaction equation

HRID 1735182 reaction equation
[CH3:1][Si:2]([CH3:14])([CH2:9][CH2:10][CH2:11][CH2:12]Cl)[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[I-:15].[Na+]>CC(C)=O>[CH3:1][Si:2]([CH3:14])([CH2:9][CH2:10][CH2:11][CH2:12][I:15])[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

Participants

4

Reactant 2

HCID 5238Sodium IodideHCID 12446018HCID 12446018, compound

Product 1

HCID 19437009HCID 19437009, compoundYield 92.6%

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

Following the same procedure as in Example 44 Step A, 5 g (19 mmol) of dimethyl-(4-chlorobutyl)-phenylsilane in 150 ml of acetone are refluxed for 60 hours with 17 g (114 mmol) of sodium iodide to afford 5.6 g (83%) of expected dimethyl-(4-iodobutyl)-phenylsilane.

Sources & evidence

ORD record
ord-6be57eb2b47e48ff905fce5897f84285
Source dataset
uspto-grants-1996_07
Patent number
US05536732

Reaction notes

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