Lithium Hydroxide → HCID 23718570, compound

HRID 1735640Notes

Reaction equation

HRID 1735640 reaction equation
[F:1][C:2]([F:14])([F:13])[S:3]([C:6]1[CH:11]=[CH:10][C:9]([OH:12])=[CH:8][CH:7]=1)(=[O:5])=[O:4].[OH-].[Li+:16]>CO>[F:13][C:2]([F:1])([F:14])[S:3]([C:6]1[CH:7]=[CH:8][C:9]([O-:12])=[CH:10][CH:11]=1)(=[O:4])=[O:5].[Li+:16]

Participants

4

Reactant 2

HCID 3939Lithium HydroxideHCID 148574264-Trifluoromethanesulfonylphenol

Product 1

HCID 23718570HCID 23718570, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

Compound (2) from Example 2, in anhydrous methanol, was neutralized with equivalent amount of lithium hydroxide: The solvent was then removed, and the residue dissolved in a small amount of anhydrous THF. Ether was subsequently added and the solution stored in a refrigerator. The precipitated crystals were filtered and washed with ether.

Workup

  1. customThe solvent was then removed
  2. dissolutionthe residue dissolved in a small amount of anhydrous THF
  3. additionEther was subsequently added
  4. filtrationThe precipitated crystals were filtered
  5. washwashed with ether

Sources & evidence

ORD record
ord-3f4a1948a30a4bb89ba92ed34638c30d
Source dataset
uspto-grants-1996_07
Patent number
US05538812

Reaction notes

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