Triethylamine → (1-(4-Cyanophenyl)-2-methylhydrazino)triphenylphosphonium Bromide

HRID 1740069Notes

Reaction equation

[C:1]([C:3]1[CH:8]=[CH:7][C:6]([NH:9][NH2:10])=[CH:5][CH:4]=1)#[N:2].[Br:11][P:12](Br)([C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1)([C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1)[C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1.[CH2:32](N(CC)CC)C>C1C=CC=CC=1>[Br-:11].[C:1]([C:3]1[CH:8]=[CH:7][C:6]([N:9]([P+:12]([C:25]2[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=2)([C:19]2[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=2)[C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)[NH:10][CH3:32])=[CH:5][CH:4]=1)#[N:2]

Participants

Conditions

Temperature: 80 °C

Procedure

A mixture of 78.9 g of 4-cyanophenylhydrazine, 250 g of dibromotriphenylphosphorane, 71.9 g of triethylamine and 1,200 ml of benzene was stirred at 80° C for 30 minutes. The resulting crystals were collected by filtration and then washed with benzene and water successively to give 261.0 g of the title compound as a colorless powder.

Workup

filtrationThe resulting crystals were collected by filtration
washwashed with benzene and water successively

Sources & evidence

ORD record: ord-8e82ed33bc424c8f8d37b10d498b3065
Source dataset: uspto-grants-1999_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05968967

Reaction notes

Loading…