Thiophenol → HCID 19010695, compound

HRID 1741764Notes

Reaction equation

HRID 1741764 reaction equation
[Cl:1][C:2]1[N:7]=[C:6](Cl)[N:5]=[C:4]([O:9][CH3:10])[N:3]=1.[C:11]1([SH:17])[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1.C(=O)(O)[O-].[Na+]>CC(C)=O>[Cl:1][C:2]1[N:3]=[C:4]([O:9][CH3:10])[N:5]=[C:6]([S:17][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)[N:7]=1

Participants

5

Reactant 3

HCID 7969ThiophenolHCID 192672,4-Dichloro-6-methoxy-3,5-triazineHCID 516892Sodium Bicarbonate

Product 1

HCID 19010695HCID 19010695, compound

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

The 2,4-dichloro-6-methoxy-s-triazine obtained according to Example A-3 is suspended, with partial solution, in 1000 parts by volume of acetone, 110 parts of thiophenol and 90 parts of sodium bicarbonate are added, and the reaction is carried out at about 20° C. After about 2 hours, the synthesis mixture is evaporated. The compound 2-chloro-4-methoxy-6-phenylthio-s-triazine is obtained as a powder containing electrolyte salt. It serves as a monochloro-triazine starting compound for the synthesis of dyestuffs according to the invention.

Workup

  1. additionare added
  2. customis carried out at about 20° C
  3. customthe synthesis mixture is evaporated

Sources & evidence

ORD record
ord-389dd7344ec74d699fc4f927eb6781e9
Source dataset
uspto-grants-1994_08
Patent number
US05334709

Reaction notes

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