1,2-Dichloroethane → HCID 129638279, compound

HRID 1751317Notes

Reaction equation

HRID 1751317 reaction equation
[CH:1]1[C:14]2[C:15]3=[C:16]4[C:11](=[CH:12][CH:13]=2)[CH:10]=[CH:9][CH:8]=[C:7]4[CH:6]=[CH:5][C:4]3=[CH:3][CH:2]=1.[C:17](Cl)(=[O:24])[C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1.Cl[CH2:27][CH2:28]Cl.[Cl-].[Al+3].[Cl-].[Cl-].[CH3:34][OH:35]>>[C:17]([C:9]1[CH:8]=[C:7]2[C:16]3=[C:15]4[C:4](=[CH:3][C:2]([C:34](=[O:35])[C:28]5[CH:27]=[CH:3][CH:2]=[CH:1][CH:14]=5)=[CH:1][C:14]4=[CH:13][CH:12]=[C:11]3[CH:10]=1)[CH:5]=[CH:6]2)(=[O:24])[C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1

Participants

6

Reactant 5

HCID 111,2-DichloroethaneHCID 887MethanolHCID 7412Benzoyl chlorideHCID 31423PyreneHCID 6451240Aluminum(III) Chloride

Product 1

HCID 129638279HCID 129638279, compound

Conditions

Temperature
60 °C

Procedure

A solution was prepared by putting 10.0 g (0.0495 mol) of pyrene, 13.9 g (0.0989 mol) of benzoyl chloride, and 87 g of 1,2-dichloroethane in a flask. Subsequently, 13.2 g (0.0989 mol) of aluminum chloride was slowly added to the solution at room temperature and then, heated up to 60° C. and agitated for 8 hours. When the reaction was complete, a precipitate was obtained by adding methanol to the resultant and filtered, obtaining dibenzoylpyrene.

Workup

  1. customA solution was prepared
  2. customa precipitate was obtained
  3. filtrationfiltered

Sources & evidence

ORD record
ord-2f98fb676d284c28adadec32e7a25af7
Source dataset
uspto-grants-2015_10
Patent number
US09158201B2

Reaction notes

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