Hexane → 2-[4-(Phenanthren-9-yl)phenyl]dibenzo[f,h]quinoxaline

HRID 1752162Notes

Reaction equation

Cl[C:2]1[CH:11]=[N:10][C:9]2[C:4](=[C:5]3[CH:19]=[CH:18][CH:17]=[CH:16][C:6]3=[C:7]3[CH:15]=[CH:14][CH:13]=[CH:12][C:8]3=2)[N:3]=1.C(O[CH2:24][CH3:25])(=O)C.[CH3:26][CH2:27][CH2:28][CH2:29][CH2:30][CH3:31]>>[CH:28]1[C:27]2[CH:18]=[C:19]([C:25]3[CH:24]=[CH:12][C:13]([C:2]4[CH:11]=[N:10][C:9]5[C:4](=[C:5]6[CH:19]=[CH:18][CH:17]=[CH:16][C:6]6=[C:7]6[CH:15]=[CH:14][CH:13]=[CH:12][C:8]6=5)[N:3]=4)=[CH:14][CH:15]=3)[C:5]3[C:4](=[CH:9][CH:8]=[CH:7][CH:6]=3)[C:26]=2[CH:31]=[CH:30][CH:29]=1

Participants

Reactant 3

HCID 8058Hexane

HCID 8857Ethyl Acetate

HCID 580194962-Chlorodibenzo[f,h]quinoxaline

Product 1

HCID 866793132-[4-(Phenanthren-9-yl)phenyl]dibenzo[f,h]quinoxaline

Procedure

The Rf values of the objective substance and 2-chlorodibenzo[f,h]quinoxaline were respectively 0.20 and 0.55, which were found by silica gel thin layer chromatography (TLC) (with a developing solvent of ethyl acetate and hexane in a ratio of 1:10).

Sources & evidence

ORD record: ord-6cfc9729740b436383b214f5225adbed
Source dataset: uspto-grants-2015_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US09162990B2

Reaction notes

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