Water → HCID 15886922, compound

HRID 1752215Notes

Reaction equation

HRID 1752215 reaction equation
[CH3:1][O:2][C:3]1[CH:4]=[CH:5][C:6]2[NH:7][C:8]3[C:13]([C:14]=2[CH:15]=1)=[CH:12][CH:11]=[CH:10][CH:9]=3.C1C(=O)N([Br:23])C(=O)C1.O>CN(C=O)C>[Br:23][C:11]1[CH:10]=[CH:9][C:8]2[NH:7][C:6]3[C:14]([C:13]=2[CH:12]=1)=[CH:15][C:3]([O:2][CH3:1])=[CH:4][CH:5]=3

Participants

5

Reactant 3

HCID 962WaterHCID 67184N-bromobutanimideHCID 5196213-Methoxy-9H-carbazole

Product 1

HCID 15886922HCID 15886922, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

3-Methoxy-9H-carbazole (Bedford, R. B.; Betham, M. J. Org. Chem. 2006, 71, 9403-9410) (0.029 g, 0.147 mmol) was dissolved in dry DMF (0.28 mL) and NBS (0.026 g, 0.147 mmol) was added to the solution. The reaction mixture was stirred at room temperature for 2 h under absence of light. The solution was poured into water (2 mL), filtered and washed with water. The title compound was isolated as a grey solid (0.033 g, 82%).

Workup

  1. filtrationfiltered
  2. washwashed with water

Sources & evidence

ORD record
ord-3d69566c8d5c4395bfedff80b408cec2
Source dataset
uspto-grants-2015_10
Patent number
US09162980B2

Reaction notes

Loading…