Glycol diglycidyl ether → HCID 131712953, compound

HRID 1758198Notes

Reaction equation

HRID 1758198 reaction equation
[CH3:1][N:2]1[C:6](=[O:7])[C:5]2([CH2:12][C:11]([CH3:14])([CH3:13])[NH:10][C:9]([CH3:16])([CH3:15])[CH2:8]2)[NH:4][C:3]1=[O:17].[O:18]1[CH2:29][CH:19]1[CH2:20][O:21][CH2:22][CH2:23][O:24][CH2:25][CH:26]1[O:28][CH2:27]1>C(O)CCCCCCC>[OH:18][CH:19]([CH2:29][N:10]1[C:11]([CH3:14])([CH3:13])[CH2:12][C:5]2([NH:4][C:3](=[O:17])[N:2]([CH3:1])[C:6]2=[O:7])[CH2:8][C:9]1([CH3:16])[CH3:15])[CH2:20][O:21][CH2:22][CH2:23][O:24][CH2:25][CH:26]([OH:28])[CH2:27][N:10]1[C:11]([CH3:13])([CH3:14])[CH2:12][C:5]2([NH:4][C:3](=[O:17])[N:2]([CH3:1])[C:6]2=[O:7])[CH2:8][C:9]1([CH3:16])[CH3:15]

Participants

4

Reactant 2

HCID 16683Glycol diglycidyl etherHCID 20510557HCID 20510557, compound

Product 1

HCID 131712953HCID 131712953, compound

Reagents, catalysts & solvents 1

HCID 9571-OctanolSolvent

Procedure

To 50 ml of n-octanol were added 5.0 g of 3,7,7,9,9-pentamethyl-1,3,8-triazaspiro[4.5]decane-2,4-dione and 1.5 g of ethylene glycol bis(2,3-epoxypropyl) ether; the mixture was then reacted as described in Example 1 to give the desired Compound No. 340 in the form of a white powder. The compound had an Rf value of 0.54 on thin-layer chromatography on silica gel developed with a 20:1:1 by volume mixture of ethyl acetate, ethanol and triethylamine.

Workup

  1. customthe mixture was then reacted

Sources & evidence

ORD record
ord-5e775860a83943ab9f01d85036583b57
Source dataset
uspto-grants-1983_02
Patent number
US04371644

Reaction notes

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