Undecylenic Acid → HCID 86738461, compound

HRID 1758900Notes

Reaction equation

HRID 1758900 reaction equation
[C:1]([OH:13])(=[O:12])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH:10]=[CH2:11].[CH2:14]([O:18][CH2:19][CH:20]=[CH2:21])[CH:15]1[O:17][CH2:16]1>C1(C)C=CC=CC=1>[CH2:14]([O:18][CH2:19][CH:20]=[CH2:21])[CH:15]1[O:17][CH2:16]1.[C:1]([OH:13])(=[O:12])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH:10]=[CH2:11]

Participants

4

Reactant 2

HCID 5634Undecylenic AcidHCID 7838Allyl glycidyl ether

Product 1

HCID 86738461HCID 86738461, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

To a suitable flask are added 165 grams of undecylenic acid, 29 grams of toluene and 2 grams of AMC-2 catalyst (Cordova Chemical Company oil soluble chromium complex). Heat is applied to the flask and when the temperature reaches 90° C., 114 grams of allyl glycidyl ether are added over a 30 minute period while holding the temperature at 90° C. At the completion of the addition, the temperature is held at 90° C. for 3 hours and 45 minutes, at which time the acid value is 0 indicating complete reaction.

Workup

  1. temperatureHeat
  2. customreaches 90° C.
  3. customat 90° C
  4. additionAt the completion of the addition
  5. custom0 indicating complete reaction

Sources & evidence

ORD record
ord-cf3bc617b0b049ec9fd4fbc2a658a9a3
Source dataset
uspto-grants-1982_07
Patent number
US04338239

Reaction notes

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