1-[4-(3-Carbomethoxyprop-2-eneoxy)phenyl]propan-2-one → 1-(4-[3-Carbomethoxypropoxy]phenyl)propan-2-one

HRID 1758988Notizen

Reaktionsgleichung

Reaktionsgleichung von HRID 1758988
[C:1]([CH:5]=[CH:6][CH2:7][O:8][C:9]1[CH:14]=[CH:13][C:12]([CH2:15][C:16](=[O:18])[CH3:17])=[CH:11][CH:10]=1)([O:3][CH3:4])=[O:2].[H][H]>C(O)C.[Pd]>[C:1]([CH2:5][CH2:6][CH2:7][O:8][C:9]1[CH:10]=[CH:11][C:12]([CH2:15][C:16](=[O:18])[CH3:17])=[CH:13][CH:14]=1)([O:3][CH3:4])=[O:2]

Komponenten

5

Edukt 2

HCID 538253751-[4-(3-Carbomethoxyprop-2-eneoxy)phenyl]propan-2-oneHCID 178418361HCID 178418361, Verbindung

Produkt 1

HCID 130796131-(4-[3-Carbomethoxypropoxy]phenyl)propan-2-oneAusbeute 99,2 %

Reagenzien, Katalysatoren, Lösungsmittel 2

HCID 23938PalladiumKatalysatorHCID 702EthanolLösungsmittel

Versuchsvorschrift

To a solution of 1-[4-(3-carbomethoxyprop-2-eneoxy)phenyl]propan-2-one (1.1 g) in ethanol (50 ml), was added 10% Pd/C (100 mg) and the mixture hydrogenated at ambient temperature and atmospheric pressure until hydrogen uptake was complete (approx. 10 minutes). The solution was filtered, evaporated to give the title compound (1.1 g) as an oil.

Aufarbeitung

  1. customhydrogenated at ambient temperature
  2. custom(approx. 10 minutes)
  3. filtrationThe solution was filtered
  4. customevaporated

Quellen und Nachweise

ORD-Eintrag
ord-5fe1d94af7b0417cb1bc3a573dc4aeb7
Quelldatensatz
uspto-grants-1982_07
Patentnummer
US04338333

Notizen zur Reaktion

Wird geladen…