Dibenzyl ether → HCID 178460687, compound

HRID 1759169Notes

Reaction equation

HRID 1759169 reaction equation
[C:1]1([CH2:7][O:8][NH2:9])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.Cl.[OH-].[Na+:12].[C:13]([CH2:16][PH:17](=[O:19])[O-:18])(=O)[CH3:14].[Na+].C(OCC1C=CC=CC=1)C1C=CC=CC=1.Cl.NO>C(O)C>[CH2:7]([O:8][N:9]=[C:13]([CH2:16][PH:17](=[O:18])[O-:19])[CH3:14])[C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Na+:12]

Participants

7

Reactant 5

HCID 7657Dibenzyl etherHCID 14798Sodium HydroxideHCID 102312Benzyloxyamine hydrochlorideHCID 443297Hydroxyamine hydrochlorideHCID 178473688HCID 178473688, compound

Product 1

HCID 178460687HCID 178460687, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

Procedure as for Example 37 using C6H5CH2ONH2HCl (4.797 g), sodium hydroxide (1.2037 g) and sodium acetylmethylphosphinate (4.331 g), except that the benzyl ether is less soluble in ethanol than hydroxylamine hydrochloride and was dissolved in 300 ml solvent.

Sources & evidence

ORD record
ord-b8032ad986034d4991c27a27c9777818
Source dataset
uspto-grants-1982_07
Patent number
US04339443

Reaction notes

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