HRID1759470

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID7187

Benzoyl peroxide

C14H10O4

2 次

HCID7501

Styrene

C8H8

HCID8846

Butyl acrylate

C7H12O2

HCID66666

1,2-Divinylbenzene

C10H10

$结构：CCCCOC(=O)/C=C\C(=O)[O-]$

HCID86595084

未命名化合物

PRODUCTS

生成物

$结构：C=CC(=O)OCCCC.C=Cc1ccccc1.C=Cc1ccccc1C=C.CCCCOC(=O)/C=C\C(=O)[O-]$

HCID86738504

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID7237

o-Xylene

C8H10

2 次

PROCEDURE

实验过程

50 parts by weight of xylene is placed in a three-necked plask, and 75 parts by weight styrene, 20 parts by weight butyl acrylate, 5 parts by weight butyl maleate, 0.6 parts by weight divinylbenzene and 0.3 parts by weight benzoyl peroxide are added through a dropping funnel under reflux over 3 hours. Then a solution of 0.3 parts by weight benzoyl peroxide in xylene is dropwise added and refluxing is continued for 3 hours followed by cooling and removing the xylene to give a styrene-butyl acrylate-butyl maleate-divinylbenzene copolymer. Gel content of the resulting polymer is 0%.

WORKUP

后处理

additionare added through a dropping funnel
temperatureunder reflux over 3 hours
temperaturerefluxing
temperatureby cooling
customremoving the xylene

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-2aeb7482661f4aa6b794e27341f75aff
来源数据集: uspto-grants-1982_07
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04340660
来源说明: uspto-grants-1982_07

反应 SMILES

[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[C:9]([O:13][CH2:14][CH2:15][CH2:16][CH3:17])(=[O:12])[CH:10]=[CH2:11].[C:18]([O:25][CH2:26][CH2:27][CH2:28][CH3:29])(=[O:24])/[CH:19]=[CH:20]\[C:21]([O-:23])=[O:22].[CH:30]([C:32]1[CH:37]=[CH:36][CH:35]=[CH:34][C:33]=1[CH:38]=[CH2:39])=[CH2:31].C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>C1(C)C(C)=CC=CC=1>[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[C:9]([O:13][CH2:14][CH2:15][CH2:16][CH3:17])(=[O:12])[CH:10]=[CH2:11].[C:18]([O:25][CH2:26][CH2:27][CH2:28][CH3:29])(=[O:24])/[CH:19]=[CH:20]\[C:21]([O-:23])=[O:22].[CH:30]([C:32]1[CH:37]=[CH:36][CH:35]=[CH:34][C:33]=1[CH:38]=[CH2:39])=[CH2:31]