Nitromethane → HCID 69532999, compound

HRID 1760903Notes

Reaction equation

HRID 1760903 reaction equation
[CH2:1]([O:7][C:8]1[CH:9]=[C:10]([CH:13]=[CH:14][C:15]=1[O:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])[CH:11]=O)[CH2:2][CH2:3][CH2:4][CH2:5][CH3:6].C([O-])(=O)C.[NH4+].[N+:28]([CH3:31])([O-:30])=[O:29]>>[N+:28]([CH:31]=[CH:11][C:10]1[CH:13]=[CH:14][C:15]([O:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH3:22])=[C:8]([O:7][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH3:6])[CH:9]=1)([O-:30])=[O:29]

Participants

4

Reactant 3

HCID 6375NitromethaneHCID 517165Ammonium AcetateHCID 118229373,4-dihexyloxybenzaldehyde

Product 1

HCID 69532999HCID 69532999, compound

Procedure

3,4-Dihexyloxybenzaldehyde (122.6 g; 0.4 mmol) is heated to 100° C. with ammonium acetate (23.12 g; 0.3 mol) and nitromethane (42.7 g; 0.7 mol). Working-up is analogous to Example 6b).

Sources & evidence

ORD record
ord-8016c7d9dc104f9b8d5da06268b446f6
Source dataset
uspto-grants-2005_01
Patent number
US06846492B2

Reaction notes

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