Lithium Hydroxide → Lithium hydroxyoctadecanoate

HRID 1761816ノート

反応式

HRID 1761816 の反応式
O[CH:2]([CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][C:13]([OH:15])=[O:14].[OH-].[Li+:23].P([O-])([O-:27])([S-])=S.[S]>>[OH:27][CH:12]([CH2:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21])[C:13]([O-:15])=[O:14].[Li+:23]

参加物

5

反応物 4

HCID 3939Lithium HydroxideHCID 778912-Hydroxystearic acidHCID 177047PhosphorodithioateHCID 5362487Sulfur

生成物 1

HCID 23668506Lithium hydroxyoctadecanoate

反応条件

温度
74 °C

実験手順

A lithium hydroxystearate grease thickener ws prepared by saponification of a mixture containing 12-hydroxystearic acid (8%) and glyceride thereof (9%) with lithium hydroxide in a mineral oil vehicle at about 174° C. in a closed contactor. After depressuring and dehydration of the thickener in an open kettle sufficient mineral oil was added to reduce the thickener content to about 9.0%. After cooling to about 74° C. a typical grease additive package, consisting of an amine antioxidant, phenolic antioxidant, metallic dithiophosphate, sulfur-containing metal deactivator and nitrogen containing antirust additives, was added.

後処理

  1. customat about 174° C.
  2. additiondehydration of the thickener in an open kettle sufficient mineral oil was added
  3. additionwas added

出典と根拠

ORDレコード
ord-81f9b79aceb34ca2baa27a286785b46f
出典データセット
uspto-grants-1989_05
特許番号
US04828732

反応ノート

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