Nickel Dichloride → HCID 86743062, compound

HRID 1762666Notes

Reaction equation

HRID 1762666 reaction equation
[CH2:1]1[CH2:11][CH2:10][N:9]2[C:4](=[N:5][CH2:6][CH2:7][CH2:8]2)[CH2:3][CH2:2]1.[Cl:12][Ni:13][Cl:14]>CC(C)=O>[CH2:1]1[CH2:11][CH2:10][N:9]2[C:4](=[N:5][CH2:6][CH2:7][CH2:8]2)[CH2:3][CH2:2]1.[Cl:12][Ni:13][Cl:14]

Participants

4

Reactant 2

HCID 24385Nickel DichlorideHCID 811841,8-Diazabicyclo(5.4.0)undec-7-ene

Product 1

HCID 86743062HCID 86743062, compoundYield 55.5%

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

152.2 g (1.0 mole) of DBU and 64.8 g(0.5 moles) of anhydrous NiCl2 were subjected to reaction at 180° C. for 4 hours in the absence of a solvent, and the reaction mixture was poured into acetone. The deposited crystals were ricovered therefrom by filtration, washed with acetone and dried, whereby 120.5 g of DBU/NiCl2 complex compound was obtained (yield: 55.5%).

Workup

  1. filtrationby filtration
  2. washwashed with acetone
  3. customdried
  4. customwhereby 120.5 g of DBU/NiCl2 complex compound was obtained (yield: 55.5%)

Sources & evidence

ORD record
ord-360451dbdb764f28810339b8404555a1
Source dataset
uspto-grants-1989_05
Patent number
US04833212

Reaction notes

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