Potassium Iodide → HCID 86736004, compound

HRID 1763815Notes

Reaction equation

HRID 1763815 reaction equation
[Cl:1][C:2]([Cl:6])=[CH:3][CH2:4]Cl.[C:7]([O-:16])(=[O:15])[CH2:8][CH2:9][CH2:10][CH2:11][C:12]([O-:14])=[O:13].[K+].[K+].[I-].[K+]>C(N(CC)CC)C>[Cl:1][CH:2]([Cl:6])[CH:3]=[CH:4][O:13][C:12](=[O:14])[CH2:11][CH2:10][CH2:9][CH2:8][C:7]([O:16][CH:4]=[CH:3][CH:2]([Cl:6])[Cl:1])=[O:15]

Participants

5

Reactant 3

HCID 4875Potassium IodideHCID 173781,1,3-TrichloropropeneHCID 9794493Potassium adipate

Product 1

HCID 86736004HCID 86736004, compound

Reagents, catalysts & solvents 1

HCID 8471TriethylamineSolvent

Procedure

62 g of 1,1,3-trichloro-propene, prepared according as described in Example 1, were reacted with 36.6 g of potassium adipate for 6 hours at 135° C. in the presence of 2 g of triethylamine and 0.3 g of potassium iodide. The reaction product was then washed and freed of the low-boiling components by means of distillation under vacuum. By a successive molecular distillation (120° C./10-4 mm Hg) 47 g of a substance were obtained which on elementary analysis showed the following composition:

Workup

  1. washThe reaction product was then washed
  2. distillationfreed of the low-boiling components by means of distillation under vacuum
  3. distillationBy a successive molecular distillation (120° C./10-4 mm Hg) 47 g of a substance
  4. customwere obtained which on elementary analysis

Sources & evidence

ORD record
ord-8bc6893574464a9c81bd96bfd0dd8dd8
Source dataset
uspto-grants-1978_09
Patent number
US04113689

Reaction notes

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