Acetone → HCID 21820147, compound

HRID 1764427Notes

Reaction equation

HRID 1764427 reaction equation
[OH-].[Na+].C(NN1[N:11]=[C:10]([Cl:12])C=C(Cl)N1)C.[N:14]1[C:21]([Cl:22])=[N:20][C:18]([Cl:19])=[N:17][C:15]=1Cl.C(=O)([O-])[O-].[Na+].[Na+].C[C:30]([CH3:32])=O>O>[CH2:30]([N:14]([C:15]1[N:11]=[C:10]([Cl:12])[N:20]=[C:18]([Cl:19])[N:17]=1)[C:15]1[N:14]=[C:21]([Cl:22])[N:20]=[C:18]([Cl:19])[N:17]=1)[CH3:32]

Participants

7

Reactant 5

HCID 180AcetoneHCID 7954Cyanuric chlorideHCID 10340Sodium CarbonateHCID 14798Sodium Hydroxide2×HCID 22768231HCID 22768231, compound

Product 1

HCID 21820147HCID 21820147, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

A solution of 0.4 g of sodium hydroxide in 4 ml of water was added dropwise with stirring over a period of 20 minutes to a solution of 1.93 g of 2-ethylamino-4,6-dichlorotriazine and 1.85 g of cyanuric chloride in 50 cc of acetone which had been cooled to 0°-5° C. Stirring was continued for 6 hours after all the sodium hydroxide solution had been added. The resulting solution was then neutralised with sodium carbonate and stirred into ice water. The precipitate was collected, dried and recrystallised from ligroin.

Workup

  1. temperaturehad been cooled to 0°-5° C
  2. customThe precipitate was collected
  3. customdried
  4. customrecrystallised from ligroin

Sources & evidence

ORD record
ord-12703c99fb1f489993334c3f289509e9
Source dataset
uspto-grants-1978_09
Patent number
US04116700

Reaction notes

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