Dimethylformamide → (2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal

HRID 1764429Notes

Reaction equation

HRID 1764429 reaction equation
C[C:2]1([OH:30])[CH:7]([OH:8])C2C=C3C(=O)C4C(=C(O)C=C(OC)C=4)C(=O)C3=[C:12]([OH:13])[C:5]=2[CH:4]([OH:27])[CH:3]1[O:28]C.CN(C)C=[O:34]>>[O:13]=[CH:12][C@@H:5]([C@H:4]([C@@H:3]([C@@H:2]([CH2:7][OH:8])[OH:30])[OH:28])[OH:27])[OH:34]

Participants

3

Reactant 2

HCID 6228DimethylformamideHCID 429826STEFFIMYCINOL

Product 1

HCID 107526(2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal

Procedure

Steffimycinol (50 mg/l), as a milled aqueous suspension or dimethylformamide solution, is added aseptically at the time of inoculation.

Sources & evidence

ORD record
ord-9df72b2bf3874044add748d7255ff5b4
Source dataset
uspto-grants-1978_09
Patent number
US04116769

Reaction notes

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