m-Chloroperbenzoic acid → HCID 22769768, compound

HRID 1764729Notes

Reaction equation

HRID 1764729 reaction equation
[CH3:1][S:2]([CH:5]([C:13]1[CH:18]=[CH:17][C:16]([Cl:19])=[CH:15][CH:14]=1)[C:6]1[CH:11]=[CH:10][C:9]([Cl:12])=[CH:8][CH:7]=1)(=[O:4])=O.Cl[C:21]1[CH:26]=CC=C(C(OO)=O)[CH:22]=1>>[CH2:1]([S:2]([CH:5]([C:13]1[CH:18]=[CH:17][C:16]([Cl:19])=[CH:15][CH:14]=1)[C:6]1[CH:11]=[CH:10][C:9]([Cl:12])=[CH:8][CH:7]=1)=[O:4])[CH2:22][CH2:21][CH3:26]

Participants

3

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 101397Benzene, 1,1'-((methylsulfonyl)methylene)bis(4-chloro-

Product 1

HCID 22769768HCID 22769768, compound

Procedure

The procedure for making bis(p-chlorophenyl)methyl methyl sulfone was followed, using a slight excess of m-chloroperbenzoic acid (0.027 mole acid to 0.025 mole of bis(p-chlorophenyl)methyl n-butyl sulfoxide). A light amber liquid was formed and this gave crystals which were recrystallized from methanol as a white solid of bis(p-chlorophenyl)methyl n-butyl sulfoxide, melting point 116°-188° C.

Workup

  1. customA light amber liquid was formed
  2. customthis gave crystals which were recrystallized from methanol as a white solid of bis(p-chlorophenyl)methyl n-butyl sulfoxide, melting point 116°-188° C.

Sources & evidence

ORD record
ord-8c78460f39714bbbba2905a15c2cf900
Source dataset
uspto-grants-1978_09
Patent number
US04117168

Reaction notes

Loading…