Toluene → HCID 17862596, compound

HRID 1766901Notes

Reaction equation

HRID 1766901 reaction equation
[CH2:1]([O:4][C:5]([O:7][CH2:8][C:9]1[CH:17]=[CH:16][CH:15]=[CH:14][C:10]=1[C:11](O)=[O:12])=[O:6])[CH:2]=[CH2:3].CN(C)C=O.C(Cl)(=O)C([Cl:26])=O.C1(C)C=CC=CC=1>ClCCl>[CH2:1]([O:4][C:5]([O:7][CH2:8][C:9]1[CH:17]=[CH:16][CH:15]=[CH:14][C:10]=1[C:11]([Cl:26])=[O:12])=[O:6])[CH:2]=[CH2:3]

Participants

6

Reactant 4

HCID 1140TolueneHCID 6228DimethylformamideHCID 65578Oxalyl chlorideHCID 21110439HCID 21110439, compound

Product 1

HCID 17862596HCID 17862596, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

2-[(Allyloxycarbonyl)oxymethyl]benzoic acid (850 mg, 3.60 mmol) obtained from Example 17-(2) was dissolved in dichloromethane (5 ml), and N,N-dimethylformamide (0.05 ml) and oxalyl chloride (570 mg) were added thereto. The mixture was stirred at room temperature for 1 hour, then toluene was added thereto, and the solution was concentrated under reduced pressure to give crude 2-[(allyloxycarbonyl)oxymethyl]benzoyl chloride.

Workup

  1. concentrationthe solution was concentrated under reduced pressure

Sources & evidence

ORD record
ord-0e3e84e525c34cc48155ef76b3260590
Source dataset
uspto-grants-2007_06
Patent number
US07230023B2

Reaction notes

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