Vinyl Acetate → HCID 18947439, compound

HRID 1769234Notes

Reaction equation

HRID 1769234 reaction equation
[SiH:1]([CH2:6][CH3:7])([CH2:4][CH3:5])[CH2:2][CH3:3].[C:8]([O:11][CH:12]=[CH2:13])(=[O:10])[CH3:9].CCOC(C)=O>C1(C)C=CC=CC=1.C1CCCCC1>[CH2:2]([Si:1]([CH2:6][CH3:7])([CH2:4][CH3:5])[CH2:13][CH2:12][O:11][C:8](=[O:10])[CH3:9])[CH3:3]

Participants

6

Reactant 3

HCID 7904Vinyl AcetateHCID 8857Ethyl AcetateHCID 12052Triethylsilane

Product 1

HCID 18947439HCID 18947439, compound

Reagents, catalysts & solvents 2

HCID 1140TolueneSolventHCID 8078CyclohexaneSolvent

Procedure

To a solution of 6.39 mL (40 mmol) of Et3SiH and 3.69 mL (40 mmol) of vinyl acetate in 40 mL of toluene is added 61.3 mg (0.16 mmol) of Rh2Cl2 (CO)4. Caution: the reaction evolves heat and gas. Within about 5 min, the reaction mixture darkens in color. Reaction is judged complete by TLC analysis (10% EtOAc in cyclohexane) after 1 h. The reaction is worked up and purified, if desired, as in example 1a.

Workup

  1. temperatureCaution: the reaction evolves heat
  2. customReaction
  3. custompurified

Sources & evidence

ORD record
ord-81d14e4a955941c3bc6228276c8044da
Source dataset
uspto-grants-1995_01
Patent number
US05380835

Reaction notes

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