Hydrochloric Acid → HCID 20096789, compound

HRID 1769571Notes

Reaction equation

HRID 1769571 reaction equation
[C:1]1([C:7]2[CH:12]=[CH:11][C:10]([C:13]3[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=3)=[CH:9][CH:8]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Cl-].[Al+3].[Cl-].[Cl-].[C:23](Cl)(=[O:33])[CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH3:32].Cl>C(Cl)Cl>[C:23]([C:4]1[CH:3]=[CH:2][C:1]([C:7]2[CH:12]=[CH:11][C:10]([C:13]3[CH:14]=[CH:15][CH:16]=[CH:17][CH:18]=3)=[CH:9][CH:8]=2)=[CH:6][CH:5]=1)(=[O:33])[CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH3:32]

Participants

6

Reactant 4

HCID 313Hydrochloric AcidHCID 7115p-TerphenylHCID 66982Decanoyl chlorideHCID 6451240Aluminum(III) Chloride

Product 1

HCID 20096789HCID 20096789, compoundYield 71.4%

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent2×

Conditions

Temperature
0 °C

Procedure

A reaction vessel was charged with 5.7 g of p-terphenyl and 40 ml of methylene chloride. To this mixture was added 4 g of anhydrous aluminum chloride with stirring at 0° C. A solution of 5.2 g of decanoyl chloride in 10 ml of methylene chloride was added dropwise. After the dropwise addition, the mixture was stirred for 5 hours. The reaction liquid was poured into diluted hydrochloric acid and the mixture was stirred well. Insolubles were collected by filtration, washed and dried to obtain 6.8 g (71%) of 4-decanoyl-p-terphenyl.

Workup

  1. additionAfter the dropwise addition
  2. stirringthe mixture was stirred for 5 hours
  3. customThe reaction liquid
  4. stirringthe mixture was stirred well
  5. filtrationInsolubles were collected by filtration
  6. washwashed
  7. customdried

Sources & evidence

ORD record
ord-730270ad12b84703875da79368d6b984
Source dataset
uspto-grants-1995_01
Patent number
US05382380

Reaction notes

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