HCID 178418750, compound → HCID 178515947, compound

HRID 1771260Notes

Reaction equation

HRID 1771260 reaction equation
[Zn:1](CC)CC.[CH:6]1[CH:25]=[CH:24][C:22](=[O:23])/[C:8](=[CH:9]/[NH:10][CH2:11][CH2:12][NH:13]/[CH:14]=[C:15]2/[CH:16]=[CH:17][CH:18]=[CH:19][C:20]/2=[O:21])/[CH:7]=1>C1COCC1>[CH:17]1[CH:18]=[CH:19][C:20](=[O:21])/[C:15](=[CH:14]/[NH:13][CH2:12][CH2:11][NH:10]/[CH:9]=[C:8]2/[CH:7]=[CH:6][CH:25]=[CH:24][C:22]/2=[O:23])/[CH:16]=1.[Zn:1]

Participants

4

Reactant 2

HCID 178418750HCID 178418750, compoundHCID 178515945HCID 178515945, compound

Product 1

HCID 178515947HCID 178515947, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Conditions

Temperature
25 °C

Procedure

The Et2Zn (0.4 ml, 1.0 M in hexane) and Salen (N′N′-bis(3-tert-butyl-5-bromo-salicylidene)-1,2-diaminocyclohexane (0.4 mmol) and were dissolved in dried THF (20 ml). The mixture was stirred under argon at 25° C. for 24 hours. After that the compound Salen-Zn was obtained.

Sources & evidence

ORD record
ord-d5ca8491425f4909912a220ef84b675a
Source dataset
uspto-grants-2016_02
Patent number
US09249120B2

Reaction notes

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