Methane → Biphenyl

HRID 1773010Notes

Reaction equation

HRID 1773010 reaction equation
C.[CH2:2](N1CCCC1=O)C.[C:10]1([C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=2)[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1.[C:22]1([NH2:29])[CH:27]=[CH:26][CH:25]=[CH:24][C:23]=1[NH2:28]>>[C:10]1([C:16]2[CH:17]=[CH:18][CH:19]=[CH:20][CH:21]=2)[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1.[C:22]1([NH2:29])[CH:27]=[CH:26][CH:25]=[CH:24][C:23]=1[NH2:28].[CH4:2]

Participants

6

Reactant 4

HCID 297MethaneHCID 7095BiphenylHCID 7243O-PhenylenediamineHCID 17595N-ethyl-2-pyrrolidone

Product 2

HCID 7095BiphenylHCID 131733384Phenylenediamine carbon black

Procedure

More specifically, an intermediate transfer coating dispersion was prepared by providing a mixture of Special Carbon Black 4, available from Orion Chemicals, the solvent N-ethyl-2-pyrrolidone (NMP), the polyamic acid of biphenyl tetracarboxylicdianhydride/phenylenediamine, and the leveling agent NOVEC™ FC-4432, a fluoro surfactant available from 3M, about 18 weight percent of solids, and which mixture was stirred and subjected to ball milling with 2 millimeter stainless steel shots via an Attritor grinding mill for 18 hours at a speed of about 200 rpm for 48 hours. There resulted a coating dispersion of the polyamic acid of biphenyl tetracarboxylicdianhydride/phenylenediamine/carbon black/leveling agent contained in NMP, where the weight ratio of polyamic acid of biphenyl tetracarboxylicdianhydride/phenylenediamine/carbon black/leveling agent was 88.8/11/0.2, and which dispersion was filtered through a 20 micron Nylon cloth filter.

Workup

  1. customMore specifically, an intermediate transfer coating dispersion was prepared
  2. customby providing
  3. customgrinding mill for 18 hours at a speed of about 200 rpm for 48 hours

Sources & evidence

ORD record
ord-ddb1fe47974a4a0991ae5c2d684f3f99
Source dataset
uspto-grants-2016_02
Patent number
US09250547B2

Reaction notes

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