Myristyl bromide → HCID 178443150, compound

HRID 1774331Notes

Reaction equation

HRID 1774331 reaction equation
[Br:1][C:2]1[CH:7]=[CH:6][C:5]([N:8]2[CH:12]=[CH:11][N:10]=[CH:9]2)=[CH:4][CH:3]=1.Br[CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27]>C1COCC1>[Br-:1].[Br:1][C:2]1[CH:3]=[CH:4][C:5]([N+:8]2[CH:12]=[CH:11][N:10]([CH2:27][CH2:26][CH2:25][CH2:24][CH2:23][CH2:22][CH2:21][CH2:20][CH2:19][CH2:18][CH2:17][CH2:16][CH2:15][CH3:14])[CH:9]=2)=[CH:6][CH:7]=1

Participants

4

Reactant 2

HCID 8208Myristyl bromideHCID 27356041-(4-Bromophenyl)imidazole

Product 1

HCID 178443150HCID 178443150, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

According to the general synthesis procedure, 4.5 mmol (1.00 g) 1-(4-bromophenyl)imidazole and 5.4 mmol (1.50 g, 1.47 ml) 1-bromotetradecane are dissolved in 5 ml THF and heated for 69 h to 90° C. After the reaction the product is precipitated with diethylether from the reaction solution.

Workup

  1. temperatureheated for 69 h to 90° C
  2. customAfter the reaction the product
  3. customis precipitated with diethylether from the reaction solution

Sources & evidence

ORD record
ord-0713c9fb51fe4631b8aee4db3b53bbb1
Source dataset
uspto-grants-2016_02
Patent number
US09260397B2

Reaction notes

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