Hydrochloric Acid → HCID 19956423, compound

HRID 1779548Notes

Reaction equation

HRID 1779548 reaction equation
[CH2:1]([N:4](C(OC(C)(C)C)=O)[CH2:5][CH2:6][CH2:7][N:8](C(OC(C)(C)C)=O)[CH2:9]/[CH:10]=[CH:11]/[CH2:12][N:13](C(OC(C)(C)C)=O)[CH2:14][CH2:15][CH2:16][N:17](C)[C:18](OC(C)(C)C)=O)[CH:2]=[CH2:3].[ClH:47]>>[ClH:47].[ClH:47].[ClH:47].[ClH:47].[CH2:1]([NH:4][CH2:5][CH2:6][CH2:7][NH:8][CH2:9]/[CH:10]=[CH:11]/[CH2:12][NH:13][CH2:14][CH2:15][CH2:16][NH:17][CH3:18])[CH:2]=[CH2:3]

Participants

3

Reactant 2

HCID 313Hydrochloric AcidHCID 19956399HCID 19956399, compound

Product 1

HCID 19956423HCID 19956423, compound

Procedure

A mixture of 0.6 g (0,916 mmol) of (E)-1-allyl-14-methyl-1,5,10,14-tetra-BOC-1,5,10,14-tetraazatetradec-7-ene and 9 ml of 3N methanolic hydrochloric acid is reacted analogously to Example 8. The resulting title compound melts at >260° C. 1H-NMR (D2O): δ2.07-2.17(m,4H); 2.73(s,3H); 3.12-3.19(m,8H); 3.69(d,2H); 3.77(d,4H); 5.48-5.55(m,2H); 5.83-5.98(m, 1H); 6.04-6.07 (m,2H).

Workup

  1. customis reacted analogously to Example 8

Sources & evidence

ORD record
ord-8e3e2e0373fe4bcda55e939667a29919
Source dataset
uspto-grants-1997_05
Patent number
US05627215

Reaction notes

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