Sodium Bicarbonate → Sodium

HRID 1788622Notes

Reaction equation

HRID 1788622 reaction equation
[N+:1]([C:4]1[CH:9]=[C:8]([N+:10]([O-:12])=[O:11])[CH:7]=[CH:6][C:5]=1CCC(O)=O)([O-:3])=[O:2].[Na:18].C(=O)([O-])O.[Na+].NC1C=C(N)C=CC=1[O:27][CH:28]([CH3:32])[C:29]([OH:31])=[O:30]>>[N+:1]([C:4]1[CH:9]=[C:8]([N+:10]([O-:12])=[O:11])[CH:7]=[CH:6][C:5]=1[O:27][CH:28]([CH3:32])[C:29]([OH:31])=[O:30])([O-:3])=[O:2].[Na:18]

Participants

6

Reactant 4

HCID 516892Sodium BicarbonateHCID 27505133-(2,4-dinitrophenyl)propanoic AcidHCID 5360545Sodium2×HCID 20189859HCID 20189859, compound

Product 2

HCID 5360545SodiumHCID 20189861HCID 20189861, compound

Procedure

The 2-(2,4-dinitrophenoxy)-propionic acid from step (a) was converted into the sodium salt with sodium hydrogen carbonate and reduced in aqueous solution, using procedures analogous to those set forth in A, and the sodium salt was then isolated. Five grams of 2-(2,4-dinitrophenoxy)-propionic acid yielded 2.4 gm of sodium salt of 2-(2,4-diaminophenoxy)-propionic acid.

Workup

  1. customwas then isolated

Sources & evidence

ORD record
ord-0ace83c6371546509178e06bffa6169c
Source dataset
uspto-grants-1987_08
Patent number
US04684371

Reaction notes

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