Sulfite → HCID 19920498, compound
Reaction equation
[S:1]([O-:4])([O-:3])=[O:2].[OH-].[Na+:6]>>[OH:3][S:1]([O-:4])=[O:2].[Na+:6].[O-:3][S:1]([O-:4])=[O:2].[Na+:6].[Na+:6]Participants
Procedure
The hollow fiber contactor was used to treat condensate from a sulphite mill as described above. In this case, a 0.05 M NaOH solution was employed instead of nitrogen to remove the SO2 and other contaminants. A 2.0 L volume of this solution was re-circulated through the system. The feed solution and nitrogen flow rates were similar to those mentioned in Example III. Results are presented in Table V. About 98% removal for SO2 was achieved compared to 84% in Table II (after 4 hours using air). The BOD, COD and TOC reductions were 63%, 57%, and 54%, respectively. Higher NaOH concentrations would allow the concentration of SO2 produced in the form of NaHSO3/Na2SO3 to be significantly higher, if so desired. The NaHSO3/Na2SO3 solution could potentially be used within the mill or sold.
Workup
- customto remove the SO2 and other contaminants
- customResults
- customAbout 98% removal for SO2
- customwas achieved compared to 84% in Table II (after 4 hours using air)
- concentrationHigher NaOH concentrations
Sources & evidence
- ORD record
- ord-68ed89538ff94350b6923c4ad90043c5
- Source dataset
- uspto-grants-2013_01
- Patent number
- US08349130B2
Reaction notes
Loading…