Sulfite → HCID 19920498, compound

HRID 1801402Notes

Reaction equation

HRID 1801402 reaction equation
[S:1]([O-:4])([O-:3])=[O:2].[OH-].[Na+:6]>>[OH:3][S:1]([O-:4])=[O:2].[Na+:6].[O-:3][S:1]([O-:4])=[O:2].[Na+:6].[Na+:6]

Participants

3

Procedure

The hollow fiber contactor was used to treat condensate from a sulphite mill as described above. In this case, a 0.05 M NaOH solution was employed instead of nitrogen to remove the SO2 and other contaminants. A 2.0 L volume of this solution was re-circulated through the system. The feed solution and nitrogen flow rates were similar to those mentioned in Example III. Results are presented in Table V. About 98% removal for SO2 was achieved compared to 84% in Table II (after 4 hours using air). The BOD, COD and TOC reductions were 63%, 57%, and 54%, respectively. Higher NaOH concentrations would allow the concentration of SO2 produced in the form of NaHSO3/Na2SO3 to be significantly higher, if so desired. The NaHSO3/Na2SO3 solution could potentially be used within the mill or sold.

Workup

  1. customto remove the SO2 and other contaminants
  2. customResults
  3. customAbout 98% removal for SO2
  4. customwas achieved compared to 84% in Table II (after 4 hours using air)
  5. concentrationHigher NaOH concentrations

Sources & evidence

ORD record
ord-68ed89538ff94350b6923c4ad90043c5
Source dataset
uspto-grants-2013_01
Patent number
US08349130B2

Reaction notes

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