Bicarbonate Ion → 2-(1-azidobut-3-enyl)-5-tosyl-5H-pyrrolo[2,3-b]pyrazine

HRID 181767Notes

Reaction equation

HRID 181767 reaction equation
[CH3:41][CH2:42][O:43][C:44]([CH3:45])=[O:46].[Cl:38][CH2:39][Cl:40].[N-:35]=[N+:36]=[N-:37].[Na+:33].[Na+:34].[O-:29][C:30]([OH:31])=[O:32].[S:1](=[O:2])(=[O:3])([c:4]1[cH:5][cH:6][c:7]([CH3:8])[cH:9][cH:10]1)[n:11]1[cH:12][cH:13][c:14]2[c:15]1[n:16][cH:17][c:18]([CH:20]([CH2:21][CH:22]=[CH2:23])[OH:24])[n:19]2.[S:25]([Cl:26])([Cl:27])=[O:28]>>[S:1](=[O:2])(=[O:3])([c:4]1[cH:5][cH:6][c:7]([CH3:8])[cH:9][cH:10]1)[n:11]1[cH:12][cH:13][c:14]2[c:15]1[n:16][cH:17][c:18]([CH:20]([CH2:21][CH:22]=[CH2:23])[N:35]=[N+:36]=[N-:37])[n:19]2

Participants

8

Reactant 7

HCID 769Bicarbonate IonHCID 923Sodium ion2×HCID 6344DichloromethaneHCID 8857Ethyl AcetateHCID 24386Thionyl ChlorideHCID 33558AzideHCID 58557357HCID 58557357, compound

Product 1

HCID 585572372-(1-azidobut-3-enyl)-5-tosyl-5H-pyrrolo[2,3-b]pyrazine

Sources & evidence

ORD record
ord-533a258e47ae4b399f20ca91e556434f
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (6/10)

Reaction notes

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