4-Acetylbiphenyl → HCID 57801044, compound

HRID 1817684Notes

Reaction equation

HRID 1817684 reaction equation
[C:1]([C:4]1[CH:9]=[CH:8][C:7]([C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)=[CH:6][CH:5]=1)(=[O:3])[CH3:2].Br[CH2:17][CH2:18][CH2:19][CH:20]=[CH2:21].[Mg]>C1COCC1>[C:7]1([C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)[CH:8]=[CH:9][C:4]([C:1]([OH:3])([CH2:21][CH2:20][CH2:19][CH:18]=[CH2:17])[CH3:2])=[CH:5][CH:6]=1

Participants

5

Reactant 3

HCID 71134-AcetylbiphenylHCID 707041-Pentene, 5-bromo-HCID 5462224Magnesium

Product 1

HCID 57801044HCID 57801044, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent2×

Procedure

4-Acetylbiphenyl (2 g) was dissolved in anhydrous THF (30 ml) and reacted with a grignard prepared from 5-bromopentene and magnesium in THF (15 ml) as described in example 23 to give the title compound as a yellow powder.

Workup

  1. customreacted with a grignard

Sources & evidence

ORD record
ord-07eb2188af314b029e199e395573484b
Source dataset
uspto-grants-2009_10
Patent number
US07598289B2

Reaction notes

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