Triphenylphosphine → HCID 55285106, compound

HRID 1818029Notes

Reaction equation

HRID 1818029 reaction equation
[N:1]([CH:4]1[CH2:9][CH2:8][CH2:7][C:6]([CH2:10][CH3:11])=[CH:5]1)=[N+]=[N-].C1(P(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1.[OH-].[K+]>>[CH2:10]([C:6]1[CH2:7][CH2:8][CH2:9][CH:4]([NH2:1])[CH:5]=1)[CH3:11]

Participants

4

Reactant 3

HCID 11776TriphenylphosphineHCID 14797Potassium HydroxideHCID 86623795HCID 86623795, compound

Product 1

HCID 55285106HCID 55285106, compound

Procedure

The title amine was generated from 3-azido-1-ethyl-cyclohexene (2.27 g, 15.00 mmol), triphenyl phosphine (4.00 g, 15.20 mmol) and KOH (0.85 g, 15.20 mmol) according to the protocols as outlined in general procedure I. Spectroscopic data: 1H NMR (300 MHz, CDCl3) δ 0.99 (t, J=7.62 Hz, 3H), 1.09-1.34 (m, 2H), 1.48-1.62 (m, 1H), 1.69-1.79 (m, 1H), 1.83-1.98 (m, 6H), 3.26-3.40 (m, 1H), 5.29-5.38 (m, 1H).

Sources & evidence

ORD record
ord-1e7af3712bd54bd1ba96e3db2f7076fe
Source dataset
uspto-grants-2009_10
Patent number
US07598417B2

Reaction notes

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