1-Octene → Tetradec-7-ene

HRID 1819562Notes

Reaction equation

HRID 1819562 reaction equation
[CH2:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]>Cl[Ru](=CC1C=CC=CC=1)([P](C1CCCCC1)(C1CCCCC1)C1CCCCC1)([P](C1CCCCC1)(C1CCCCC1)C1CCCCC1)Cl.CCCCCC>[CH3:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH:7]=[CH:8][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH3:6]

Participants

4

Reactant 1

HCID 81251-Octene

Product 1

HCID 25209Tetradec-7-eneYield 80%

Reagents, catalysts & solvents 2

HCID 178479819HCID 178479819, compoundCatalystHCID 8058HexaneSolvent

Procedure

A mixture of 1-octene (7.15 g, 64 mmol) and Grubbs' catalyst (0.030 g, 0.04 mmol, 0.0006 equ) was stirred under a static vacuum for 15 hours, then passed through a plug of silica eluting with hexane. Concentration gave tetradec-7-ene (4.982 g, 80%) as a colourless liquid.

Workup

  1. concentrationConcentration

Sources & evidence

ORD record
ord-059bfbb3bdb943b8b53ba4481f757dce
Source dataset
uspto-grants-2009_10
Patent number
US07601754B2

Reaction notes

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