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HRID1828380

反应详情

EQUATION

反应方程式

HRID 1828380 的结构方程式

REACTANTS

反应物

4
结构：NC(N)=O
HCID1176

Urea

CH4N2O

结构：O=[N+]([O-])c1cc([N+](=O)[O-])c(O)c([N+](=O)[O-])c1
HCID6954

Picric acid

C6H3N3O7

结构：O=c1[nH]c(=O)[nH]c(=O)[nH]1
HCID7956

Cyanuric acid

C3H3N3O3

2 次

结构：Nc1c([N+](=O)[O-])cc([N+](=O)[O-])cc1[N+](=O)[O-]
HCID10271

2,4,6-Trinitroaniline

C6H4N4O6

2 次

PRODUCTS

生成物

2
结构：NC(N)=O
HCID1176

Urea

CH4N2O

结构：O=[N+]([O-])c1cc([N+](=O)[O-])c([O-])c([N+](=O)[O-])c1.[NH4+]
HCID8577

Ammonium picrate

C6H6N4O7

AUXILIARIES

试剂、催化剂与溶剂

1
结构：O=S1(=O)CCCC1
溶剂HCID31347

Sulfolane

C4H8O2S

2 次

PROCEDURE

实验过程

A slurry of picric acid (2.29 g, 0.01 mol ) and urea (1.80 g, 0.03 mol) in sulfolane (2 mL) is heated (167° C.) in a closed pressure vessel for 23 h. 13C-NMR analysis indicates quantitative conversion to picramide and cyanuric acid. Under the same conditions, ammonium picrate (2.46 g, 0.01 mol) and urea (1.80 g, 0.03 mol) in sulfolane (2 mL) gave a complete conversion to picramide and cyanuric acid.