Hydrogen Peroxide → HCID 501150, compound

HRID 1829726Notes

Reaction equation

HRID 1829726 reaction equation
[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([CH3:8])=[CH:4][C:3]=1[CH:9]([S:17][C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][N+:19]=1[O-:24])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16].C(#N)C.[OH-:28].[Na+].[OH:30]O>CO>[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([CH3:8])=[CH:4][C:3]=1[CH:9]([S:17]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][N+:19]=1[O-:24])(=[O:30])=[O:28])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]

Participants

6

Reactant 4

HCID 784Hydrogen PeroxideHCID 6342AcetonitrileHCID 14798Sodium HydroxideHCID 501151HCID 501151, compound

Product 1

HCID 501150HCID 501150, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

To a solution of 34.3 gm (0.1 mol) 2-[1-(2,5-dimethylphenyl) octylthio]pyridine N-oxide and 10.7 gm (0.26 mol) acetonitrile in 400 ml of methanol was added sufficient NaOH solution (6 N to minimize water) to adjust the pH in the operating range of 9.0 to 9.5 (true), approximately 11–12 (meter). 17 gm (0.26 mol) of 50% hydrogen peroxide was added in increments.

Sources & evidence

ORD record
ord-6f2822d255a64758898ae87d09091e1c
Source dataset
uspto-grants-2006_06
Patent number
US07064139B2

Reaction notes

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