Benzyl mercaptan → HCID 501219, compound

HRID 1829731Notes

Reaction equation

HRID 1829731 reaction equation
[Cl:1][C:2]1[CH:3]=[CH:4][CH:5]=[N+:6]([O-:8])[CH:7]=1.[CH2:9]([SH:16])[C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1.C1C=C(Cl)C=C(C(OO)=O)C=1>C(Cl)(Cl)Cl>[C:10]1([CH2:9][S:16][C:5]2[CH:4]=[CH:3][C:2]([Cl:1])=[CH:7][N+:6]=2[O-:8])[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1

Participants

5

Reactant 3

HCID 7509Benzyl mercaptanHCID 70297m-Chloroperbenzoic acidHCID 123133Pyridine, 3-chloro-, 1-oxide

Product 1

HCID 501219HCID 501219, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent2×

Procedure

As described in U.S. Pat. No. 4,394,155, Example 1, 2-(phenylmethylthio)-5-chloropyridine N-oxide is prepared from 5-chloropyridine N-oxide and benzylmercaptan. To a well stirred solution of 2.5 g (9.01 mol) of the thio compound in 25 mL chloroform is added 4 g (0.02 mol) of MCPBA in 50 mL chloroform.

Sources & evidence

ORD record
ord-5ea368f3c8144d839c98b473e99d9ec2
Source dataset
uspto-grants-2006_06
Patent number
US07064139B2

Reaction notes

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