Thiophenol → 3-Chloropropyl phenyl sulfide

HRID 1832741Notes

Reaction equation

HRID 1832741 reaction equation
[C:1]1([SH:7])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.Br[CH2:9][CH2:10][CH2:11][Cl:12]>>[Cl:12][CH2:11][CH2:10][CH2:9][S:7][C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

3

Reactant 2

HCID 7969ThiophenolHCID 80061-Bromo-3-chloropropane

Product 1

HCID 2696063-Chloropropyl phenyl sulfide

Procedure

Prepared by Procedure R and Scheme Z using benzenethiol and 1-bromo-3-chloropropane: 1H NMR (400 MHz, CDCl3) δ 7.37–7.34 (m, 2H), 7.32–7.26 (m, 2H), 7.19 (tt, 1H, J=1.4, 7.3 Hz), 3.67 (t, 2H, J=6.6 Hz), 3.08 (t, 2H, J=6.6 Hz), 2.06 (qt, 2H, J=6.6 Hz).

Workup

  1. customPrepared by Procedure R and Scheme Z

Sources & evidence

ORD record
ord-923c9235f9fd4a5d9a83a573b7b91266
Source dataset
uspto-grants-2006_06
Patent number
US07067534B1

Reaction notes

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