Cyclohexanone → HCID 68432283, compound
Reaction equation
[C:1]1(=[O:7])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[OH:8][C:9]1C=CC([C:15]2[CH:20]=[CH:19][C:18]([C:21]#[N:22])=[CH:17][CH:16]=2)=C[CH:10]=1.[O:23]1[CH2:27][CH2:26][O:25][CH2:24]1>CC(N=NC(C#N)(C)C)(C#N)C>[CH2:9]([O:8][C:1](=[O:7])[CH:6]=[CH2:5])[CH3:10].[C:24]([OH:25])(=[O:23])[C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:21]([C:18]1[CH:17]=[CH:16][CH:15]=[CH:20][C:19]=1[C:27]1[CH:26]=[CH:3][CH:2]=[CH:1][CH:6]=1)#[N:22]Participants
Reactant 3
Product 1
Reagents, catalysts & solvents 1
Procedure
A coating solution was prepared for the coating procedure. 8.21 grams of cyanobiphenyl benzoate ethyl acrylate was polymerized with 0.80 grams of LC 756 in 27.1 grams of dioxolane (commercially available from Aldrich Chemical Co., Milwaukee, Wis.) using 0.29 grams of Vazo 52 (commercially available from Dupont, Wilmington, Del.) as a thermal initiator. This reaction was run for 16 hours at 60° C. This solution was then combined with 15 grams of cyclohexanone (commercially available from Aldrich Chemical Co., Milwaukee, Wis.), 15.4 grams of LC 242, 0.64 grams of LC 756, 2.24 grams of 4′-hydroxy-1,1′-biphenyl-4-carbonitrile (commercially available from Aldrich Chemical Co., Milwaukee, Wis.), 27.1 grams of dioxolane (commercially available from Aldrich Chemical Co., Milwaukee, Wis.), 0.11 grams of butylated hydroxyl toluene (BHT is commercially available from Aldrich Chemical Co., Milwaukee, Wis.), 0.28 grams of Irgacure 819 (commercially available from Ciba Geigy, Hawthorne, N.Y.), and 0.84 grams of phenyl ethyl acrylate (commercially available from Polysciences, Warrington, Pa.).
Workup
- customA coating solution was prepared for the coating procedure
Sources & evidence
- ORD record
- ord-0bf0c2da745645f89fc68b311e45feb5
- Source dataset
- uspto-grants-2006_06
- Patent number
- US07068344B2
Reaction notes
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