Bromobenzene → HCID 21387556, compound

HRID 1833855Notes

Reaction equation

OC(C1OC=CC=1)C1C=CC=CC=1.[C:14]([C:17]1[O:18][CH:19]=[CH:20][CH:21]=1)(=[O:16])[CH3:15].BrC1C=CC=CC=1.[CH3:29][O:30][C:31]1[CH:36]=[CH:35][CH:34]=[CH:33][C:32]=1Br>>[O:18]1[CH:19]=[CH:20][CH:21]=[C:17]1[C:14]([C:32]1[CH:33]=[CH:34][CH:35]=[CH:36][C:31]=1[O:30][CH3:29])([OH:16])[CH3:15]

Participants

Reactant 4

HCID 7961Bromobenzene

HCID 113582-Bromoanisole

HCID 145052-Acetylfuran

HCID 37463482-Furyl(phenyl)methanol

Product 1

HCID 21387556HCID 21387556, compound

Procedure

(±)1-(2-Furyl)-1-(2-methoxyphenyl)ethanol (b.p. 115°-118° C./0.15 mm.Hg; m.p. 64°-66° C.) was prepared by the procedure hereinbefore described in (i) for the preparation of (±) 2-α-hydroxybenzylfuran but replacing the furfuraldehyde by 2-acetylfuran [described by Levine et al, J.A.C.S. 71, 1208,(1949)] and the bromobenzene by 2-methoxybromobenzene.

Sources & evidence

ORD record: ord-103bbaad6fd148848939e13b00634701
Source dataset: uspto-grants-1978_01
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04067723

Reaction notes

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