Ethylamine → HCID 54208625, compound

HRID 1833970Notes

Reaction equation

HRID 1833970 reaction equation
[CH3:1][C:2]1[CH:11]=[CH:10][C:9]2[C:4](=[CH:5][CH:6]=[CH:7][CH:8]=2)[C:3]=1O.P(OC1C=CC=CC=1)(OC1C=CC=CC=1)OC1C=CC=CC=1.[CH2:35]([NH2:37])[CH3:36]>>[CH3:1][C:2]1[CH:11]=[CH:10][C:9]2[C:4](=[CH:5][CH:6]=[CH:7][CH:8]=2)[C:3]=1[NH:37][CH2:35][CH3:36]

Participants

4

Reactant 3

HCID 6341EthylamineHCID 7540Triphenyl phosphiteHCID 240552-Methyl-1-naphthol

Product 1

HCID 54208625HCID 54208625, compoundYield 85%

Procedure

316 parts of 2-methyl-α-naphthol, 10 parts of triphenyl phosphite and 115 parts of ethylamine gas are heated for 20 hours at 230° C in a pressure autoclave. The further working up is carried out as described in Example 3. 315 parts of 2-methyl-N-ethyl-α-naphthylamine, boiling at 120° - 125° C/0.3 mm Hg (nD25 = 1.6145) are obtained, corresponding to a yield of 85% of theory.

Sources & evidence

ORD record
ord-2b7cc687b3d74e2f89376a2840b71f3c
Source dataset
uspto-grants-1978_01
Patent number
US04067903

Reaction notes

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